At level 40 your backstab dagger should be best-in-slot or close to it, with hitroll packed into every slot that accepts it. Endgame hunting is competitive; know your tweak targets before you camp a mob.

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Backstab dagger

Melee weapon

Light

Neck

Body

Legs

Feet

Hands

Arms

Shield

About

Waist

Wrist

Finger

Hold

Aura

Hip